Targeted energy transfers in vibro-impact oscillators for seismic mitigation

In the field of seismic protection of structures, it is crucial to be able to diminish ‘as much as possible’ and dissipate ‘as fast as possible’ the load induced by seismic (vibration-shock) energy imparted to a structure by an earthquake. In this context, the concept of passive nonlinear energy pumping appears to be natural for application to seismic mitigation. Hence, the overall problem discussed in this paper can be formulated as follows: Design a set of nonlinear energy sinks (NESs) that are locally attached to a main structure, with the purpose of passively absorbing a significant part of the applied seismic energy, locally confining it and then dissipating it in the smallest possible time. Alternatively, the overall goal will be to demonstrate that it is feasible to passively divert the applied seismic energy from the main structure (to be protected) to a set of preferential nonlinear substructures (the set of NESs), where this energy is locally dissipated at a time scale fast enough to be of practical use for seismic mitigation. It is the aim of this work to show that the concept of nonlinear energy pumping is feasible for seismic mitigation. We consider a two degree-of-freedom (DOF) primary linear system (the structure to be protected) and study seismic-induced vibration control through the use of Vibro-Impact NESs (VI NESs). Also, we account for the possibility of attaching to the primary structure additional alternative NES configurations possessing essential but smooth nonlinearities (e.g., with no discontinuities). We study the performance of the NESs through a set of evaluation criteria. The damped nonlinear transitions that occur during the operation of the VI NESs are then studied by superimposing wavelet spectra of the nonlinear responses to appropriately defined frequency – energy plots (FEPs) of branches of periodic orbits of underlying Conservative systems.     

Corrigendum to “New algebraic properties of an amalgamated algebra along an ideal”

At some point, after publication, we realized that Proposition 4.1(2) and Theorem 4.4 in [2 D’Anna, M., Finocchiaro, C. A., Fontana, M. (2016). New algebraic properties of an amalgamated algebra along an ideal. Commun. Algebra 44(5):1836–1851.[Taylor & Francis Online], [Web of Science ®] , [Google Scholar]] hold under the assumption (not explicitly declared) that B = f(A)+J. Furthermore, we provide here the exact value for the embedding dimension of A?^fJ, also when B≠f(A)+J, under the hypothesis that J is finitely generated as an ideal of the ring f(A)+J.     

Volatile organic compound adsorption on a nonporous silica surface: how do different probe molecules sense the same surface?

In this work, we compare experimental results to molecular simulation results of volatile organic compound (VOC) adsorption on nonporous silica. We adopted an effective model for the rough solid surface, obtained by a temperature annealing scheme, plus an experimental/simulation nitrogen adsorption tuning process over the silica energetic oxygen parameter. The measurement/prediction of selected VOCs, specifically, n-pentane and methylcyclohexane, is presented in terms of adsorption isotherms, with an emphasis on the angle distribution analysis of the three studied probe molecules with respect to the same modeled surface.     

A simplified Quick, Easy, Cheap, Effective, Rugged and Safe approach for the determination of trihalomethanes and benzene, toluene, ethylbenzene and xylenes in soil matrices by fast gas chromatography with mass spectrometry detection

A method based on simplified QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) extraction followed by large-injection volume-fast gas chromatography and mass spectrometry detection has been developed for the determination of trihalomethanes (chloroform, bromodichloromethane, dibromochloromethane and bromoform) and BTEX (benzene, toluene, ethylbenzene and xylenes) in soil samples.The simplified version of QuEChERS used meets the requirements of the “green chemistry” and provides reliable results with high sample throughput, low solvent consumption, little labour and the use of materials commonly employed in laboratories. The GC device used is equipped with a programmable temperature vaporizer (PTV), with a liner packed with Tenax-TA^®. Using the solvent-vent mode, the PTV allows the injection of large volumes of sample, affording an improvement in the sensitivity of the method. The chromatographic conditions used here allowed the separation of the compounds in less than 5.50 min. Good linearity was obtained for all the target compounds, with highly satisfactory repeatability and reproducibility values. The limits of detection were in the 0.2 to 15 μg kg⁻¹ range. The method was validated by the analysis of two certified reference materials.     

New Triterpenoid and Ergostane Glycosides from the Leaves of Hydrocotyle umbellata L.

Two new triterpenoid glycosides, together with two new ergostane glycosides, umbellatosides A–D ( 1 – 4 , resp.), have been isolated from the leaves of Hydrocotyle umbellata L. Their structures were established by 2D‐NMR spectroscopic techniques (¹H,¹H‐COSY, TOCSY, NOESY, HSQC, and HMBC) and mass spectrometry as 3β,22β‐dihydroxy‐3‐O‐[α‐L ‐rhamnopyranosyl‐(1→2)‐β‐D ‐glucuronopyranosyl]olean‐12‐en‐28‐oic acid 28‐O‐β‐D ‐glucopyranosyl ester ( 1 ), 3‐O‐[α‐L ‐rhamnopyranosyl‐(1→2)‐β‐D ‐glucuronopyranosyl]oleanolic acid 28‐O‐β‐D ‐glucopyranosyl ester ( 2 ), (3β,11α,26)‐ergosta‐5,24(28)‐diene‐3,11,26‐triol 3‐O‐(β‐D ‐glucopyranosyl)‐11‐O‐(α‐L ‐rhamnopyranosyl)‐26‐O‐β‐D ‐glucopyranoside ( 3 ), and (3β,11α,21,26)‐ergosta‐5,24(28)‐diene‐3,11,21,26‐tetrol 3‐O‐(β‐D ‐glucopyranosyl)‐11‐O‐(α‐L ‐rhamnopyranosyl)‐26‐O‐β‐D ‐glucopyranoside ( 4 ).     

Complex formation between imidazole and carboxylate ligands in aqueous solution

We report the results of a potentiometric study on the formation of weak complexes between imidazole (im) and acetate, malonate, and citrate (L), at T=25°C. Formation of protonated species H_j (im)(L), in which j=1 for acetate, j=1, 2 for malonate and j=1, 2, 3 for citrate, was found. The formation of weak complexes between N-ligands and O-ligands may be used to interpret the behavior of these classes of compounds in natural fluid and/or in biological systems, as regards inter-or intra-molecular interactions.     

Multi-Conjugate Adaptive Optics for ELTs: constraints and limitations

We present how enlarging the size of a telescope from the current 10 meter telescope to the future 100 meter Extremely Large Telescopes increases the complexity of a classical or multiconjugate adaptive optics instrument. We point out elements or parameters of the system for which it is critical to propose new ideas as solutions and we study the effect of the increase of the diameter on the point spread function of an MCAO and a Ground Layer AO system. To cite this article: R. Ragazzoni et al., C. R. Physique 6 (2005).     

Substituent effects on the kinetics of the cerium(IV) oxidation of mandelic acids in sulfate media. Anomalous kinetic behavior of the methoxy derivative

The kinetics of the cerium(IV) oxidation of p-nitro and p-methoxymandelic acids have been investigated in H₂SO₄-MHSO₄ (M⁺ = Li⁺, Na⁺, K⁺) and H₂SO₄-MClO₄ (M⁺ = H⁺, Na⁺) mixtures at a constant total electrolyte concentration of 2.00 mol/dm³. The oxidation of p+nitromandelic acid proceeds through two [H⁺]-independent paths, as was also observed for some substituted mandelic acids studied previously. The kinetic behavior of the p-methoxy derivative differs from that of the other mandelic acids in that (1) the oxidation occurs via two [H⁺]-dependent paths, (2) the reaction rate is anomalously high, (3) the activation enthalpy and entropy of the overall process are markedly lower. It provides strong support to the suggestion that a different mechanism is operative. The substituent effects and the reaction mechanism are discussed.